تهیه و مطالعه مولکولی کمپلکس Cu(DPT)2 با پرتو x(HDPT = 1،3- دی فنیل تری ازن

I ,3 -Diphenyltriazene (HDPT) reacts with NaH in THF and generates the sodium salt (NaDPT). Further reaction of [Cu(fMEDA)h[CuCld with one equivalent of this ligand in THF leads to the formation of a dimeric Cu (I) complex, (Cu(DPT)h. The moleculat structure has been determine(! by using single -crystal X-ray diffraction method. The orange complex crystallizes in monoclinic space group C2Jc with four molecules per unit cell. The unit cell dimensions are a=26.184(12), b=5.564(2), and c= 15.695(5)A WilhP= 116.51(3)". The final R value is 0.054 for 2050 reflections measured. Cootdination number around each copper is two (nearly linear). The Cu-Cu distance is 2.447(2)A.